Physical chemistry

  • States of Matter: Gases; Introduction; Law of equipartition of energy; Collision diameter; Collision number; Collision frequency and mean free path;
  • Viscosities of gases; Measurements; Effect of temperature and pressure on viscosities of gasses;
  • Critical phenomenon of gases and experimental determination of Pc; Vc and Tc;
  • The Joule-Thomson Experiment;
  • Liquefying Gases Using an Isoenthalpic Expansion.
  • Kinetic theory of Gases:
  • Maxwell distribution law of molecular velocities;
  • Derivation of most probable; Mean and root mean square velocities;
  • Transport properties; Effect of altitude; Molar mass and temperature on vertical distribution of particle;
  • Liquids: The properties of liquids like surface tension;
  • Viscosity; Refractive index and dipole moment;
  • Parachor, Reheochor and molar refraction as additive and constitutive properties;
  • Measurement of refractive index and dipole moment;
  • Solids: Symmetry operations and Bravis lattices;
  • Thermal Conduction. Ionic Conduction;
  • Concept of X-Ray diffraction; Bragg’s equation and crystal structure analysis;
  • Crystal structure of metallic solids; Ionic solids; Molecular solids and covalent networks;
  • Heat capacities of solids.
  • Chemical Equilibrium Basic concepts;
  • Law of mass action,
  • relationship between different equilibrium constants ,
  • homogenous and heterogeneous equilibria,
  • Le-Chatelier’s principle,
  • Gibbs energies of formation and calculations of equilibrium constants,
  • effect of temperature and pressure on the equilibrium constants/compositions,
  • van’t Hoff equation;
  • Equilibria Involving Ideal Gases and Solid or Liquid Phases;

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